Saturday, 6 October 2012

Polycarbonate -Sheets-Sheds-Domes In Amritsar-Punjab-India

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This Is The Blog For Roofing-Polycarbonate-Sheets-Domes-Sheds-In-Amritsar-Punjab-India

Structure And Fitting


Polycarbonates received their name because they are polymers containing carbonate groups (–O–(C=O)–O–). Most polycarbonates of commercial interest are derived from rigid monomers. A balance of useful features including temperature resistance, impact resistance and optical properties position polycarbonates between commodity plastics and engineering plastics.

 

 Production


The main polycarbonate material is produced by the reaction of bisphenol A and phosgene COCl2. The

 
(HOC6H4)2CMe2 + 2 NaOH → (NaOC6H4)2CMe2 + 2 H2O



overall reaction can be written as follows:
Polycarbonatsynthese.svg
The first step of the synthesis involves treatment of bisphenol A with sodium hydroxide, which deprotonates the hydroxyl groups of the bisphenol A.[4]

 
(NaOC6H4)2CMe2 + COCl2 → 1/n [OC(OC6H4)2CMe2]n + 2 NaCl




The diphenoxide ((NaOC6H4)2CMe2) reacts with phosgene to give a chloroformate, which subsequently is attacked by another phenoxide. The net reaction from the diphenoxide is:


In this way, approximately one billion kilograms of polycarbonate is produced annually. Many other diols have been tested in place of bisphenol A, e.g. 1,1-bis(4-hydroxyphenyl)cyclohexane and dihydroxybenzophenone. The cyclohexane is used as a comonomer to suppress crystallisation tendency of the BPA-derived product. Tetrabromobisphenol A is used to enhance fire resistnce. Tetramethylcyclobutanediol has been developed as a replacement for BPA.[4]
An alternative route to polycarbonates entails transesterification from BPA and diphenyl carbonate:
(HOC6H4)2CMe2 + (C6H5O)2CO → 1/n [OC(OC6H4)2CMe2]n + 2 C6H5OH
The diphenyl carbonate was derived in part from carbon monoxide, this route being greener than the phosgene method.[4]


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New Fibre House,Amritsar,Punjab,India.

1 comment:

  1. Polycarbonate provide you with an unparalleled view of the sky while protecting you from the adverse effects of too much exposure to sunlight and its harmful UV rays.
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